The transition away from the production and consumption of high global warming potential (GWP) hydrofluorocarbons (HFCs) under the 2016 Kigali Amendment to the Montreal Protocol on Substances that Deplete the Ozone Layer has prompted air conditioning, refrigeration, and heat pump equipment manufacturers to seek alternative refrigerants with lower direct climate impacts. Additional factors affecting alternative refrigerant choice include safety (i.e., flammability and toxicity), environmental, and thermodynamic constraints. At the same time, manufacturers are incentivized to seek refrigerants with higher energy efficiency, which saves on electricity costs and reduces indirect greenhouse gas emissions from electricity generation. The life cycle climate performance (LCCP) metric is commonly used to assess the combined direct and indirect climate impacts of refrigerant-use equipment. Here, we consider an additional impact on climate performance: the degradation of refrigerant in equipment, i.e., the direct climate impacts of high-GWP byproducts that can form as the result of adding trifluoroiodomethane (CF3I) to refrigerant blends to reduce flammability. Such a production of high-GWP gases could change the acceptability of CF3I-containing refrigerants. Further, it highlights the need to understand refrigerant degradation within equipment in calculations of the environmental acceptability of new cooling technology.
This paper addresses what has been described as a primary concern related to patents: even if chemical companies in Montreal Protocol Article 5 Parties can develop their own methods of producing low-GWP refrigerant hydrofluoroolefin (HFO) or using them in the products they make, they could be prevented (absent a license) from selling their products at home and in key markets abroad in countries where restrictive patents have been granted to other companies, at least until the time when challenges to patents are decided or these patents expire.
This paper reviews the status of patents granted on HFO-1234yf in automotive air conditioning (AC) in the US, Europe, and China, covering the largest automotive manufacturing regions in the world. This paper primarily focuses on patents on the use of HFO-1234yf in automobiles, as opposed to patents on the manufacture of HFO-1234yf.
This paper presents a pioneering benefit assessment framework and indicative quantification of the community and national benefits of operating cost savings from super-efficient room air conditioning (RAC) that are spent locally and not for imported fuel, electricity, and power plants. It also estimates the benefits of expanded employment to replace and service the new RACs and to recover and destroy obsolete and contaminated ozone-depleting and greenhouse gas (GHG) refrigerants. Shifting spending from foreign to local purchase improves balance of trade, strengthens domestic currency, and creates jobs and prosperity as funds circulate in the local economy. Added to that are the community benefits of mass replacement of RACs and their service to maintain energy efficiency over the life of the appliance. This community impact grows over time as savings accumulate on avoided fuel and energy infrastructure and as the income from the new jobs circulates in the local economy.
